• NT CAT PC-8 CAS No.:98-94-2 Synthesis method and application
    Rm1104 ,No. 258, West SongXing Road, BaoShan District, Shanghai, China.
    NT CAT PC-8 CAS No.:98-94-2 Synthesis method and application

    Brief introduction.
    Chemical Chinese name: N,N-dimethylcyclohexylamine
    Chemical English name: N,N-dimethylcyclohexylamine; dimethyl aminocy clohexane
    Chemical Alias: Dimethyl aminocyclohexane
    CAS No.: 98-94-2
    EC No.: 202-715-5
    Molecular formula: C8H17N

    Synthesis method.
    N,N-dimethylaniline catalytic chlorination method
    In 1904, Sabatier et al. carried out the gas-phase hydrogenation of N,N a dimethylamine at a temperature of 160-180°C and at atmospheric pressure to produce DMCHA.

    Phenol method
    This method uses Pd or Rh as the catalyst, and phenol dimethylamine and hydrogen as raw materials. For example, when Pd is the catalyst, the catalyst dosage is 0.2~0.5, and the process conditions are 60~150℃, hydrogen pressure 0.15~0.48MPa, reaction time 6h, and the yield is between 70~80%. The raw material is available, and the reaction conditions are mild, but the catalyst is made of precious metals, and the yield is low.

    Cyclohexylamine method
    The process also uses formaldehyde and formic acid to react with cyclohexylamine, or uses oxides of Bi, Sb, Mg, A1, Lu, etc. as catalysts to react cyclohexylamine with methanol to methylate cyclohexylamine to produce DMCHA. the disadvantage of this method is the low selectivity of the former reaction, and the yield of the later methylation is not high.

    Cyclohexanone method
    Among the methods for the synthesis of DMCHA, the reductive amination method using cyclohexanone as raw material has more advantages: high conversion, yield and selectivity. The processes using Pd/C catalyst or Cu-A1 catalyst have their own characteristics and are currently under development in China.

    Uses.
    [Use I] Mainly used as polyurethane hard foam catalyst
    [Use II] N,N-dimethylcyclohexylamine can be used in a wide range of rigid foams. N,N-Dimethylcyclohexylamine is also suitable for the manufacture of rigid foam furniture frames and decorative parts. It can be used as the main catalyst alone in rigid foam products without the addition of organotin, or it can be supplemented with JD series catalysts according to the process and product requirements. It is also used as intermediate of rubber accelerator and synthetic fiber.
    Use III】It is used as intermediate of dyestuff, used to make vanillin, azo dyestuff, triphenylmethane dyestuff, also can be used as solvent, stabilizer, analysis reagent, etc.. Also used as catalyst.

    Storage and transportation.
    Should be sealed and stored in a dry, cool and ventilated warehouse

    Package: 200KG/drum
    200KG/drum Storage: It is recommended to store in dry and cool area with proper ventilation. Please fasten the lid as soon as possible after original packaging to prevent the mixing of other substances such as moisture and other substances from affecting the product performance. Do not inhale dust and avoid skin and mucous membrane contact. Smoking, eating and drinking are prohibited in the workplace. After work, shower and change clothes. Store contaminated clothes separately and wash them before use. Maintain good hygiene habits.

    More:https://www.newtopchem.com/archives/40458
    Technical support and business contacts E-mail:info@newtopchem.com
    NT CAT PC-8 CAS No.:98-94-2 Synthesis method and application Brief introduction. Chemical Chinese name: N,N-dimethylcyclohexylamine Chemical English name: N,N-dimethylcyclohexylamine; dimethyl aminocy clohexane Chemical Alias: Dimethyl aminocyclohexane CAS No.: 98-94-2 EC No.: 202-715-5 Molecular formula: C8H17N Synthesis method. N,N-dimethylaniline catalytic chlorination method In 1904, Sabatier et al. carried out the gas-phase hydrogenation of N,N a dimethylamine at a temperature of 160-180°C and at atmospheric pressure to produce DMCHA. Phenol method This method uses Pd or Rh as the catalyst, and phenol dimethylamine and hydrogen as raw materials. For example, when Pd is the catalyst, the catalyst dosage is 0.2~0.5, and the process conditions are 60~150℃, hydrogen pressure 0.15~0.48MPa, reaction time 6h, and the yield is between 70~80%. The raw material is available, and the reaction conditions are mild, but the catalyst is made of precious metals, and the yield is low. Cyclohexylamine method The process also uses formaldehyde and formic acid to react with cyclohexylamine, or uses oxides of Bi, Sb, Mg, A1, Lu, etc. as catalysts to react cyclohexylamine with methanol to methylate cyclohexylamine to produce DMCHA. the disadvantage of this method is the low selectivity of the former reaction, and the yield of the later methylation is not high. Cyclohexanone method Among the methods for the synthesis of DMCHA, the reductive amination method using cyclohexanone as raw material has more advantages: high conversion, yield and selectivity. The processes using Pd/C catalyst or Cu-A1 catalyst have their own characteristics and are currently under development in China. Uses. [Use I] Mainly used as polyurethane hard foam catalyst [Use II] N,N-dimethylcyclohexylamine can be used in a wide range of rigid foams. N,N-Dimethylcyclohexylamine is also suitable for the manufacture of rigid foam furniture frames and decorative parts. It can be used as the main catalyst alone in rigid foam products without the addition of organotin, or it can be supplemented with JD series catalysts according to the process and product requirements. It is also used as intermediate of rubber accelerator and synthetic fiber. Use III】It is used as intermediate of dyestuff, used to make vanillin, azo dyestuff, triphenylmethane dyestuff, also can be used as solvent, stabilizer, analysis reagent, etc.. Also used as catalyst. Storage and transportation. Should be sealed and stored in a dry, cool and ventilated warehouse Package: 200KG/drum 200KG/drum Storage: It is recommended to store in dry and cool area with proper ventilation. Please fasten the lid as soon as possible after original packaging to prevent the mixing of other substances such as moisture and other substances from affecting the product performance. Do not inhale dust and avoid skin and mucous membrane contact. Smoking, eating and drinking are prohibited in the workplace. After work, shower and change clothes. Store contaminated clothes separately and wash them before use. Maintain good hygiene habits. More:https://www.newtopchem.com/archives/40458 Technical support and business contacts E-mail:info@newtopchem.com
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  • TMEDA (N,N,N',N'-Tetramethylethylenediamine) CAS No.:110-18-9
    Rm1104 ,No. 258, West SongXing Road, BaoShan District, Shanghai, China.
    TMEDA (N,N,N',N'-Tetramethylethylenediamine)
    CAS No.:110-18-9

    Over view
    Common Name: N,N,N',N'-Tetramethylethylenediamine
    Other Chemical Names: N,N,N',N'-Tetramethylethane-1,2-diamine, electrophoresis grade;Four MethylEthylenediaMine;N,N,N',N'-TetraMethylethylenediaMine
    Molar formular C6H16N2
    Molar mass 116.2


    Physical and chemical properties:
    a) Appearance Form: Transparent colorless liquid
    b) Melting point/freezing point Melting point/range: -55 °C - lit.
    c) Initial boiling point and
    boiling range 120 - 122 °C - lit.
    d) Flash point 20 °C - closed cup
    e) Evaporation rate no data available
    f) Flammability (solid, gas) no data available
    g) Upper/lower
    flammability or
    explosive limits Upper explosion limit: 9,08 %(V)
    Lower explosion limit: 0,98 %(V)
    h) Relative density 0,775 g/cm3 at 20 °C
    i) Water solubility soluble
    j) Partition coefficient: log Pow: 0,3


    Features and uses:
    NT CAT TMEDA is a colorless-to-straw, liquid, tertiary amine with a characteristic aminic odor. It is readily soluble in water, ethyl alcohol, and other organic solvent.
    It is used as an intermediate in organic synthesis. It is also used as a cross linking catalyst for polyurethane rigid foams.

    Storage Information
    NEWTOP Chemical recommends that our catalysts be stored in a dry and cool area under appropriate ventilation conditions. Each container should be closed tightly to avoid contamination with moisture or other negative influences that could change the products’ performance in the end use.

    Package:
    160KG Steel Drum

    (Toyocat TE/ Kaolizer 11/ Dabco TMEDA)
    More:https://www.newtopchem.com/archives/41215
    TMEDA (N,N,N',N'-Tetramethylethylenediamine) CAS No.:110-18-9 Over view Common Name: N,N,N',N'-Tetramethylethylenediamine Other Chemical Names: N,N,N',N'-Tetramethylethane-1,2-diamine, electrophoresis grade;Four MethylEthylenediaMine;N,N,N',N'-TetraMethylethylenediaMine Molar formular C6H16N2 Molar mass 116.2 Physical and chemical properties: a) Appearance Form: Transparent colorless liquid b) Melting point/freezing point Melting point/range: -55 °C - lit. c) Initial boiling point and boiling range 120 - 122 °C - lit. d) Flash point 20 °C - closed cup e) Evaporation rate no data available f) Flammability (solid, gas) no data available g) Upper/lower flammability or explosive limits Upper explosion limit: 9,08 %(V) Lower explosion limit: 0,98 %(V) h) Relative density 0,775 g/cm3 at 20 °C i) Water solubility soluble j) Partition coefficient: log Pow: 0,3 Features and uses: NT CAT TMEDA is a colorless-to-straw, liquid, tertiary amine with a characteristic aminic odor. It is readily soluble in water, ethyl alcohol, and other organic solvent. It is used as an intermediate in organic synthesis. It is also used as a cross linking catalyst for polyurethane rigid foams. Storage Information NEWTOP Chemical recommends that our catalysts be stored in a dry and cool area under appropriate ventilation conditions. Each container should be closed tightly to avoid contamination with moisture or other negative influences that could change the products’ performance in the end use. Package: 160KG Steel Drum (Toyocat TE/ Kaolizer 11/ Dabco TMEDA) More:https://www.newtopchem.com/archives/41215
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  • PU catalyst: MB20 CAS#: 34364-26-6
    Rm1104 ,No. 258, West SongXing Road, BaoShan District, Shanghai, China.
    PU catalyst: MB20 CAS#: 34364-26-6

    Overview:
    Common Name: BISMUTH NEODECANOATE
    Other Chemical Names: Neodecanoicacid,bismuth(3+)salt;neodecanoicacid,bismuth(3++)salt;BISMUTHNEODECANOATE;BISMUTH(III)NEODECANOATE;bismuth(3+)neodecanoate;BISMUChemicalbookTHNEODECANOATE,TECH;Bismuth(III)neodecanoate,superconductorgrade~60%inneodecanoicacid(15-20%Bi);Bismuth(III)neodecanoate,superconductorgrade

    a) Appearance and Properties: Liquid
    Color: light yellow transparent
    b) Boiling point, initial boiling point and boiling range 180 °C
    c) Flash point 158 °C - closed cup
    d) Evaporation rate No data available
    e) Flammability (solid, gas) no data available
    f) high/low flammability or explosiveness limits no data available
    g) Vapor pressure 0.60mmHg at 21 °C
    h) Vapour density No data available
    i) Density/relative density 1.22 g/cm3 at 25 °C
    j) water soluble insoluble
    k)n-octanol/water partition coefficient no data available
    l) Autoignition temperature no data available
    m) Decomposition temperature no data available
    n) Viscosity 50mPa.s at 25 °C

    Features and uses:
    MB20 is used as a catalyst in the polyurethane industry, showing high catalytic activity, and is widely applicable to spray, high density elastomer, and microcellular elastomer systems. Has the following characteristics:
    A powerful gel catalyst to promote the completion of the reaction in the later stage;
    It shows that the viscosity of the system is delayed when the level of intermolecular reaction is low in the early stage of the reaction;
    Environmentally friendly products that can replace lead and tin-containing catalysts;
    In the common polyurethane reaction system, the microcellular elastomer system and the high-density semi-rigid foam system enhance the stability of the system reaction.
    Acts as a co-catalyst with a tertiary amine to accelerate the urethane reaction and cure. Exhibits delayed viscosity build on front-end at low usage level while promoting excellent back-end cure. It is free of mercury, lead and dibutyl tin. Possesses low volatility with little or no odor. It has compatibility with common rigid and flexible foam polyols.
    It is an alternative to tin-based catalysts in flexible slabstock, high-density flexible foams, spray, microcellular, and rigid foam systems.
    Storage Information
    Recommends that our catalysts be stored in a dry and cool area under appropriate ventilation conditions. Each container should be closed tightly to avoid contamination with moisture or other negative influences that could change the products' performance in the end use.
    Package:
    25kg/Plastic Drum, 200KG/Steel Drum, 1000kg/IBC Drum

    More:https://www.newtopchem.com/archives/39757
    PU catalyst: MB20 CAS#: 34364-26-6 Overview: Common Name: BISMUTH NEODECANOATE Other Chemical Names: Neodecanoicacid,bismuth(3+)salt;neodecanoicacid,bismuth(3++)salt;BISMUTHNEODECANOATE;BISMUTH(III)NEODECANOATE;bismuth(3+)neodecanoate;BISMUChemicalbookTHNEODECANOATE,TECH;Bismuth(III)neodecanoate,superconductorgrade~60%inneodecanoicacid(15-20%Bi);Bismuth(III)neodecanoate,superconductorgrade a) Appearance and Properties: Liquid Color: light yellow transparent b) Boiling point, initial boiling point and boiling range 180 °C c) Flash point 158 °C - closed cup d) Evaporation rate No data available e) Flammability (solid, gas) no data available f) high/low flammability or explosiveness limits no data available g) Vapor pressure 0.60mmHg at 21 °C h) Vapour density No data available i) Density/relative density 1.22 g/cm3 at 25 °C j) water soluble insoluble k)n-octanol/water partition coefficient no data available l) Autoignition temperature no data available m) Decomposition temperature no data available n) Viscosity 50mPa.s at 25 °C Features and uses: MB20 is used as a catalyst in the polyurethane industry, showing high catalytic activity, and is widely applicable to spray, high density elastomer, and microcellular elastomer systems. Has the following characteristics: A powerful gel catalyst to promote the completion of the reaction in the later stage; It shows that the viscosity of the system is delayed when the level of intermolecular reaction is low in the early stage of the reaction; Environmentally friendly products that can replace lead and tin-containing catalysts; In the common polyurethane reaction system, the microcellular elastomer system and the high-density semi-rigid foam system enhance the stability of the system reaction. Acts as a co-catalyst with a tertiary amine to accelerate the urethane reaction and cure. Exhibits delayed viscosity build on front-end at low usage level while promoting excellent back-end cure. It is free of mercury, lead and dibutyl tin. Possesses low volatility with little or no odor. It has compatibility with common rigid and flexible foam polyols. It is an alternative to tin-based catalysts in flexible slabstock, high-density flexible foams, spray, microcellular, and rigid foam systems. Storage Information Recommends that our catalysts be stored in a dry and cool area under appropriate ventilation conditions. Each container should be closed tightly to avoid contamination with moisture or other negative influences that could change the products' performance in the end use. Package: 25kg/Plastic Drum, 200KG/Steel Drum, 1000kg/IBC Drum More:https://www.newtopchem.com/archives/39757
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  • PU Catalyst: BDMA (benzyldimethylamine) CAS:103-83-3
    Rm1104 ,No. 258, West SongXing Road, BaoShan District, Shanghai, China.
    PU Catalyst: BDMA (benzyldimethylamine) CAS:103-83-3

    Over view:
    Common Name: Benzyl Dimethyl Amine
    Other Chemical Names: N,N-Dimethylbenzylamine, Benzenemethamine, N,N-dimethyl-;Benzenemethanamine,N,N-dimethyl-;Benzylamine,

    Physical and chemical properties:
    Appearance Form: transprant light yellow liquid
    Odour no data available
    PH 10 at 10 g/l at 20 °C
    Melting point/freezing point Melting point/range: -75 °C - lit.
    Initial boiling point and boiling range 181 - 184 °C at 1.020 hPa - lit.
    Flash point 53 °C - closed cup
    Evaporation rate no data available
    Flammability (solid, gas) Upper explosion limit: 6,3 %(V)
    Upper/lower flammability
    or explosive limits Lower explosion limit: 0,9 %(V)
    Relative density 0,9 g/cm3 at 25 °C
    Water solubility soluble
    Partition coefficient: noctanol/water log Pow: 1,87
    Molar formular C9H13N
    Molar mass 135.21

    Features and uses:
    A liquid tertiary amine catalyst. Can improve foam cure and demolding time. It is an excellent candidate to consider for use in water-NCO reaction in rigid polyurethane foams.
    BDMA is typically suitable to replace DMCHA in formulations using a high level of water as blowing or co-blowing agent can reduce surface friability and improve adhesion of foam to substrates.
    BDMA promotes the urethane reaction and is commonly used in high-water rigid foam applications to reduce friability. It has a characteristic but low amine odor, and is soluble in water and in most organic solvents.
    BDMA is used in flexible slabstock and rigid foam applications.
    It promotes the urethane reaction and is commonly used in high-water rigid foam applications to reduce friability.
    BDMA is also used for flexible slabstock foam applications.
    Storage Information
    Recommends that our catalysts be stored in a dry and cool area under appropriate ventilation conditions. Each container should be closed tightly to avoid contamination with moisture or other negative influences that could change the products' performance in the end use.

    Package:
    180KG/Steel Drum
    (DABCO BDMA/Niax BDMA/ PC Cat NP60/ Addocat DB/ Jeffcat BDMA/ Lupragen N103)

    More :https://www.newtopchem.com/archives/516
    PU Catalyst: BDMA (benzyldimethylamine) CAS:103-83-3 Over view: Common Name: Benzyl Dimethyl Amine Other Chemical Names: N,N-Dimethylbenzylamine, Benzenemethamine, N,N-dimethyl-;Benzenemethanamine,N,N-dimethyl-;Benzylamine, Physical and chemical properties: Appearance Form: transprant light yellow liquid Odour no data available PH 10 at 10 g/l at 20 °C Melting point/freezing point Melting point/range: -75 °C - lit. Initial boiling point and boiling range 181 - 184 °C at 1.020 hPa - lit. Flash point 53 °C - closed cup Evaporation rate no data available Flammability (solid, gas) Upper explosion limit: 6,3 %(V) Upper/lower flammability or explosive limits Lower explosion limit: 0,9 %(V) Relative density 0,9 g/cm3 at 25 °C Water solubility soluble Partition coefficient: noctanol/water log Pow: 1,87 Molar formular C9H13N Molar mass 135.21 Features and uses: A liquid tertiary amine catalyst. Can improve foam cure and demolding time. It is an excellent candidate to consider for use in water-NCO reaction in rigid polyurethane foams. BDMA is typically suitable to replace DMCHA in formulations using a high level of water as blowing or co-blowing agent can reduce surface friability and improve adhesion of foam to substrates. BDMA promotes the urethane reaction and is commonly used in high-water rigid foam applications to reduce friability. It has a characteristic but low amine odor, and is soluble in water and in most organic solvents. BDMA is used in flexible slabstock and rigid foam applications. It promotes the urethane reaction and is commonly used in high-water rigid foam applications to reduce friability. BDMA is also used for flexible slabstock foam applications. Storage Information Recommends that our catalysts be stored in a dry and cool area under appropriate ventilation conditions. Each container should be closed tightly to avoid contamination with moisture or other negative influences that could change the products' performance in the end use. Package: 180KG/Steel Drum (DABCO BDMA/Niax BDMA/ PC Cat NP60/ Addocat DB/ Jeffcat BDMA/ Lupragen N103) More :https://www.newtopchem.com/archives/516
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